The effect of sliding speed, wear track diameter and sliding distance
on the wear behaviour of a diamond-like carbon (DLC) coating deposited
using magnetron sputtering from a carbon target at very high ion curr
ent density has been investigated applying experimental design and sta
tistical variance analysis. It has been shown that sliding speed has a
highly significant effect on wear rate of the DLC coating. Within the
sliding speed range studied (0.048 to 0.45 m s(-1)), a U-shaped parab
olic curve for the relationship between specific wear rate and sliding
speed has been observed with a minimum wear rate at a speed of approx
imately 0.25 m s(-1). There is a significant negative effect from the
combination of sliding speed and distance on wear rate which indicates
the involvement of some time-related processes in wear mechanisms for
the DLC coating. A model is presented based on the assumption that th
e control step in the generation of wear debris particles is the chemi
cally activated debonding at the crack tip due to the presence of some
reactive species. A semi-quantitative expression for the relationship
between the specific wear rate and sliding speed has been derived. Re
asonably good agreement between this expression and experimental resul
ts was obtained. (C) 1998 Elsevier Science S.A. All rights reserved.