This paper deals with the investigation of two-step salt bath nitrocar
burizing technologies. For comparison, ferritic nitrocarburizing was a
lso conducted. By means of metallographic examination, microhardness t
est, X-ray diffraction analysis, the microstructure, phase constructio
n, surface hardness and hardness profiles of case hardened layers on s
teel treated by various nitrocarburizing techniques were investigated.
The friction coefficient and ring-on-block apparatuses were employed
to investigate the friction coefficient and wear-resistance of case ha
rdened layers. Meanwhile, the surface roughness of various nitrocarbur
ized specimens was also tested by a stylus profilometer. The experimen
tal results indicate that thicker compound layers are achieved on the
specimen surfaces treated by two-step nitrocarburizing than by ferriti
c nitrocarburizing; the phase constructions of two-step salt bath nitr
ocarburized specimen surfaces are different from that observed on ferr
itic nitrocarburized specimens and two distinct layers are clearly vis
ible on the cross-sections of two-step nitrocarburized specimens which
consists predominately of epsilon-compound (Fe3N) with a tiny minorit
y of Fe3O4 (outer layer) and carbon/nitrogen martensite with a high pe
rcentage of austenite (inner later), while the phase construction of s
pecimen surfaces treated by ferritic nitrocarburizing is composed main
ly of epsilon-compound (Fe3N) and a small amount of Fe4N and Fe2-3N. (
C) 1998 Elsevier Science S.B. All rights reserved.