Upgrading an existing post-ozonation plant with two-step granular acti
vated carbon (GAC) filtration for assimilable organic carbon (AOC) rem
oval was studied. The effects of ozone dose on AOC formation and its r
emoval in the subsequent two-step GAC filtration was studied using che
mically pretreated 2 to 14 degrees C humic lake water. Two parallel pi
lot-plant trains with different ozone doses (0 to 1.2 mgO(3)/mgTOC) an
d a short-term ozonation study were performed. The optimum ozone dose
for maximum AOC formation was 0.4-0.5 mgO(3)/mgTOC. The AOC-P17 of ozo
nated water was three-fold higher and AOC-NOX over ten-fold higher tha
n in non-ozonated water, while the following biofiltration (first step
) removed 51% and 72% of AOC-P17 and AOC-NOX, respectively. The adsorb
er (second step) contributed to less than 10% of the overall AOC reduc
tion. It appeared that biofiltration is a feasible method in upgrading
water treatment plants for AOC removal even when treating cold humic
waters, while the subsequent adsorber seems to have less significance
for AOC removal. (C) 1998 IAWQ. Published by Elsevier Science Ltd.