LATTICE MODEL CALCULATION OF THE STRAIN-ENERGY DENSITY AND OTHER PROPERTIES OF CRYSTALLINE LICOO2

The strain energy densities for various crystalline planes of LiCoO2 w ere calculated from the stiffness tensors obtained from lattice model calculations using the program GULP. In addition to Coulomb and Buckin gham potentials, it was necessary to include shell models for the oxyg en and cobalt ions in order to obtain acceptable agreement between the observed and calculated structural parameters and high frequency diel ectric constant. The strain energy densities u due to differential the rmal expansion were calculated using the theoretical stiffness tensors and estimated values for the thermal expansion coefficients of LiCoO2 . For a temperature change of 675 degrees C, these ranged from 0.5 to 1.3x10(8) erg/cm(3) or 5 to 13 J/m(2) for 1-mu m-thick films on alumin a substrates. In particular, the energies for the (003), (101), and (1 04) planes were ordered as u(003)>>u(104) >u(101). This suggests that the strong (101) preferred orientation of LiCoO2 films (greater than o r equal to 1 mu m thick) is due to the tendency to minimize volume str ain energy that arises from differential thermal expansion between the film and the substrate. Additional properties obtained from the GULP calculations include the free energy, heat capacity, and the k=0 vibra tional modes.