It is shown that semi-insulating GaAs diodes exhibit all the qualitati
ve electrical properties expected from a relaxation semiconductor. The
degree of ideality increases after irradiation by neutrons for liquid
encapsulated Czochralski and liquid phase epitaxy (LPE) material alth
ough LPE material is almost lifetimelike directly from manufacture. Ex
perimental results are shown for current-voltage and capacitance-volta
ge frequency over a range of temperatures for samples in the low- and
high-space charge limit conditions. The implications for commercial Ga
As and other compound semiconductor devices are discussed. (C) 1998 Am
erican Institute of Physics.