FIRST SPECTROSCOPIC EVIDENCE FOR MOLECULAR HCL ON A LIQUID SURFACE WITH SUM-FREQUENCY GENERATION

Authors
BALDELLI S SCHNITZER C SHULTZ MJ
Citation
S. Baldelli et al., FIRST SPECTROSCOPIC EVIDENCE FOR MOLECULAR HCL ON A LIQUID SURFACE WITH SUM-FREQUENCY GENERATION, The Journal of chemical physics, 108(23), 1998, pp. 9817-9820
Citations number
56
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
108
Issue
23
Year of publication
1998
Pages
9817 - 9820
Database
ISI
SICI code
0021-9606(1998)108:23<9817:FSEFMH>2.0.ZU;2-3
Abstract
Sum frequency generation spectroscopy has been used to obtain the vibr ational spectrum of HCl on the surface of a liquid. HCl was studied on the surface of 96 wt % H2SO4, 12 M HCl solution, liquid HCl and glass , of which only liquid HCl produces a resonant signal. Implications fo r the form of HCl on surfaces and the reactions in the atmosphere are discussed. (C) 1998 American Institute of Physics.