ASSESSMENT OF MTO AS A CATALYST FOR THE SYNTHESIS OF ACID-SENSITIVE EPOXIDES - USE OF THE BIPHASIC SYSTEM H2O2 CH2CL2 WITH AND WITHOUT BIPYRIDINE AND INFLUENCE OF THE SUBSTITUENTS ON THE DOUBLE-BONDS/

Authors
RUDLER H GREGORIO JR DENISE B BREGEAULT JM DELOFFRE A
Citation
H. Rudler et al., ASSESSMENT OF MTO AS A CATALYST FOR THE SYNTHESIS OF ACID-SENSITIVE EPOXIDES - USE OF THE BIPHASIC SYSTEM H2O2 CH2CL2 WITH AND WITHOUT BIPYRIDINE AND INFLUENCE OF THE SUBSTITUENTS ON THE DOUBLE-BONDS/, Journal of molecular catalysis. A, Chemical, 133(3), 1998, pp. 255-265
Citations number
21
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis. A, Chemical → ACNP
ISSN journal
13811169
Volume
133
Issue
3
Year of publication
1998
Pages
255 - 265
Database
ISI
SICI code
1381-1169(1998)133:3<255:AOMAAC>2.0.ZU;2-U
Abstract
Methyltrioxorhenium (MTO) catalyzes the selective epoxidation of alken es in the biphasic medium CH2Cl2/H2O2-H2O. Especially sensitive epoxid es, which could not be obtained by the use of other reagents, have bee n isolated in high yield by the addition of bipyridine to this reactio n medium. (C) 1998 Elsevier Science B.V. All rights reserved.