Contact electrification measurements using atomic force microscopy tec
hniques were performed using micrometer-sized spheres made of polystyr
ene and flat substrates of either freshly cleaved, highly oriented pyr
olytic graphite (HOPG) or a 0.2-mu m-thick Au[lll] film grown on mica.
The polystyrene/HQPG interaction exhibited significant electrostatic
charging when compared to the polystyrene/Au system. This result is co
nsistent with qualitative expectations of contact charging based on a
triboelectric series of common materials. The observed contact electri
fication is also consistent: with electronic charge transfer between m
aterials, rather than an ionic dr material transfer mechanism. (C) 199
8 American Institute of Physics.