MOLECULAR-SIEVING OF N-BUTENES BY MICROPOROUS SILICOALUMINOPHOSPHATES

Authors
RICHTER M ROOST U LOHSE U
Citation
M. Richter et al., MOLECULAR-SIEVING OF N-BUTENES BY MICROPOROUS SILICOALUMINOPHOSPHATES, Journal of the Chemical Society, Chemical Communications, (21), 1993, pp. 1616-1617
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
21
Year of publication
1993
Pages
1616 - 1617
Database
ISI
SICI code
0022-4936(1993):21<1616:MONBMS>2.0.ZU;2-R
Abstract
Of all three n-butenes (but-1-ene, cis-but-2-ene and trans-but-2-ene) only the trans-isomer can easily access the pore system of the molecul ar sieve SAPO-17 resulting in appreciable adsorption and allowing a pr omising adsorptive separation of stereoisomeric butenes at temperature s of 330-395 K, where catalytic reactions do not occur.