THE EFFECT OF STRONG NHS HYDROGEN-BONDS IN THE COPPER(I) THIOLATE COMPLEX, (NET4)2[CU(O-PABT)3] (O-PABT = O-PIVALOYLAMINOBENZENETHIOLATO)

Authors
OKAMURA T UEYAMA N NAKAMURA A AINSCOUGH EW BRODIE AM WATERS JM
Citation
T. Okamura et al., THE EFFECT OF STRONG NHS HYDROGEN-BONDS IN THE COPPER(I) THIOLATE COMPLEX, (NET4)2[CU(O-PABT)3] (O-PABT = O-PIVALOYLAMINOBENZENETHIOLATO), Journal of the Chemical Society, Chemical Communications, (21), 1993, pp. 1658-1660
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
21
Year of publication
1993
Pages
1658 - 1660
Database
ISI
SICI code
0022-4936(1993):21<1658:TEOSNH>2.0.ZU;2-G
Abstract
Short Cu-S bonds, induced by strong intramolecular NH...S hydrogen bon ds, have been established by X-ray analysis, IR spectra, and EHMO calc ulations for (NEt4)2[Cu(I)(o-pabt)3] (o-pabt = o-pivaloylaminobenzenet hiolato) and suggest an important role for this type of hydrogen bondi ng in blue copper proteins.