UNEXPECTED P-O BOND FORMATION IN THE REACTION OF PPH2CL WITH THE TRIIRON CLUSTER [PPH4][FE3(CO)9(MU-H)(MU-CME-EQUIVALENT-TO-CPH)]

Authors
ROS J YANEZ R TORRES MR PERALES A MATHIEU R
Citation
J. Ros et al., UNEXPECTED P-O BOND FORMATION IN THE REACTION OF PPH2CL WITH THE TRIIRON CLUSTER [PPH4][FE3(CO)9(MU-H)(MU-CME-EQUIVALENT-TO-CPH)], Journal of the Chemical Society, Chemical Communications, (21), 1993, pp. 1667-1668
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
21
Year of publication
1993
Pages
1667 - 1668
Database
ISI
SICI code
0022-4936(1993):21<1667:UPBFIT>2.0.ZU;2-1
Abstract
PPh2Cl reacts with [PPh4][Fe3(CO)s(mu-H)(mu-CMe=CPh)] at room temperat ure to give a new compound [Fe2(CO)6{mu-PPh2OC(H)C(Me)C(Ph)}] containi ng the PPh2OC(H)C(Me)C(Ph) bridging ligand, the X-ray structure of whi ch has been determined.