BENZYLTRIPHENYLPHOSPHONIUM PEROXODISULFATE (PHCH2PPH3)(2)S2O8 - A MILD AND INEXPENSIVE REAGENT FOR EFFICIENT OXIDATION OF ORGANIC-COMPOUNDSUNDER NONAQUEOUS AND APROTIC CONDITIONS

Authors
MOHAMMADPOORBALTORK I HAJIPOUR AR MOHAMMADI H
Citation
I. Mohammadpoorbaltork et al., BENZYLTRIPHENYLPHOSPHONIUM PEROXODISULFATE (PHCH2PPH3)(2)S2O8 - A MILD AND INEXPENSIVE REAGENT FOR EFFICIENT OXIDATION OF ORGANIC-COMPOUNDSUNDER NONAQUEOUS AND APROTIC CONDITIONS, Bulletin of the Chemical Society of Japan, 71(7), 1998, pp. 1649-1653
Citations number
29
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
71
Issue
7
Year of publication
1998
Pages
1649 - 1653
Database
ISI
SICI code
0009-2673(1998)71:7<1649:BP(-AM>2.0.ZU;2-B
Abstract
Benzyltriphenylphosphonium peroxodisulfate is an easily prepared and s table reagent. It could be used as an oxidant under aprotic and nonaqu eous conditions in organic solvents. This reagent oxidizes different c lasses of alcohols to carbonyl compounds, thiols to disulfides, sulfid es to sulfoxides, oximes to carbonyl compounds and aromatic amines to azo compounds efficiently, alpha-Hydroxy carboxylic acids and phenylac etic acids undergo oxidative decarboxylation to produce carbonyl compo unds.