R. Shi et al., INTERFACIAL MICROSTRUCTURES OF INTRABUNDLE IN AS-RECEIVED CARBON CARBON COMPOSITES PREPARED BY CVI/, Carbon (New York), 36(9), 1998, pp. 1331-1335
A detailed study of the interfacial microstructures of the intrabundle
s in as-received carbon/carbon composites prepared by CVI was performe
d by high resolution electron microscopy. Two kinds of carbon fibers,
high strength carbon fiber T300 and high modulus carbon fiber T-50, we
re chosen for comparison. It was found that the interface between the
carbon fiber and carbon matrix is not simply a mechanical pinning stru
cture formed by pyrolytic carbons directly contacting the rough carbon
fiber surface. A transitional interfacial layer between the carbon fi
bers and the pyrolytic carbon matrix was observed which is referred to
as induced microstructure. The graphitic degree and the crystallite s
ize of the carbon fiber surface markedly affect the induced interfacia
l microstructures. The more regular and graphitic the carbon fiber sur
face, the more ordered and thicker the interface layer induced. (C) 19
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