Activated carbons were prepared from an Australian bituminous coal in
this study. The preparation process consisted of phosphoric acid impre
gnation followed by carbonization in nitrogen at 400-600 degrees C for
1-3 hours. The results reveal that the surface area and pore volume o
f the resulting carbons increase with the chemical ratio, H3PO4/coal.
Within the ranges of carbonization temperature and time, the chemicall
y activated carbon prepared from carbonization at 500 degrees C for 3
hours was found to have maximum surface area and pore volume values. P
hysical activation with CO2 of the initially H3PO4 activated carbon wa
s examined and the results suggest that the combined activation is sui
table for producing high porosity carbons with a high proportion of me
soporosity. (C) 1998 Elsevier Science Ltd. All rights reserved.