PRELIMINARY-RESULTS OF THE STUDIES ON FRACTIONATION OF YTTERBIUM ISOTOPES IN YB(III)-ACETATE YB-AMALGAM SYSTEM/

Citation
W. Dembinski et al., PRELIMINARY-RESULTS OF THE STUDIES ON FRACTIONATION OF YTTERBIUM ISOTOPES IN YB(III)-ACETATE YB-AMALGAM SYSTEM/, Separation science and technology, 33(11), 1998, pp. 1693-1701
Citations number
20
Categorie Soggetti
Engineering, Chemical",Chemistry
ISSN journal
01496395
Volume
33
Issue
11
Year of publication
1998
Pages
1693 - 1701
Database
ISI
SICI code
0149-6395(1998)33:11<1693:POTSOF>2.0.ZU;2-P
Abstract
Preliminary data on the fractionation of ytterbium isotopes in a Yb(II I)-acetate/Yb-amalgam exchange system were obtained. The light isotope was preferentially fractionated to the amalgam phase. The values of t he unit separation gain per mass difference, epsilon, were found to be - 0.00054 for Yb-176/171 and -0.00069 for Yb-176/174. The difference, which amounted to 0.00015, may be taken as evidence for the occurrenc e of the so-called ''even-odd'' effect. It was also found that the che mical isotope shift of ytterbium was mirrored by the optical isotope s hift in its atomic spectra.