This letter addresses the broadening mechanism of the near-band-gap ph
otoluminescence in GaN films doped n type with silicon. The films were
produced by plasma assisted molecular beam epitaxy and their carrier
concentration was varied systematically from 10(15) to 10(20) cm(-3).
The photoluminescence was excited with a 10 mW He-Cd laser at 77 K. At
low carrier concentration (<10(17) cm(-3)) the photoluminescence peak
has a full width at half maximum of about 18 meV, while at high carri
er concentration (>10(18) cm(-3)) the full width at half maximum incre
ases monotonically with carrier concentration up to about 120 meV. The
broadening of the line at high carrier concentration is attributed to
tailing of the density of states caused by potential fluctuations due
to randomly distributed impurities, The data were quantitatively anal
yzed, as a function of carrier concentration and compensation ratio, u
sing the impurity band broadening model of Morgan [Phys. Rev. 139, A34
3 (1965)], and the agreement between model and experimental data suppo
rts the model's validity and suggests a potential method of determinin
g the compensation in degenerate nitride semiconductors. (C) 1998 Amer
ican Institute of Physics.