Rg. Kulkarni et al., CERAMIC PROCESSING, DOPANT-SITE OCCUPANCIES AND SUPERCONDUCTING PROPERTIES OF YBA2(CU1-XFEX)3OZ, Physica. C, Superconductivity, 217(1-2), 1993, pp. 175-181
We provide a recipe to process oxygen-rich Fe-doped YBa2Cu3O7-delta sa
mples, which display unusual Fe-dopant site occupancies and supercondu
cting properties. Specifically, we observe substantial occupation of a
chain-associated quasi-octahedral site (site E). Room-temperature agi
ng of such samples at ambient conditions leads to the extinction of si
te E and a concomitant growth of other chain sites, and an increase in
T(c). The aged samples display the usual Fe-dopant site distribution
and T(c)'s reported by numerous groups for this superconductor.