ON THE ANODIC DEHYDRODIMERIZATION OF TRIA CYLMETHANES - SYNTHESIS ANDREACTIONS OF SUBSTITUTED 4,7,8-TRIOXABICYCLO[3.2.1]OCTENES

Authors
THOMAS HG WELLEN U SIMONS J RAABE G
Citation
Hg. Thomas et al., ON THE ANODIC DEHYDRODIMERIZATION OF TRIA CYLMETHANES - SYNTHESIS ANDREACTIONS OF SUBSTITUTED 4,7,8-TRIOXABICYCLO[3.2.1]OCTENES, Synthesis, (11), 1993, pp. 1113-1120
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
11
Year of publication
1993
Pages
1113 - 1120
Database
ISI
SICI code
0039-7881(1993):11<1113:OTADOT>2.0.ZU;2-I
Abstract
Beta-Tricarbonylic compounds 1 can be oxidized anodically in acetonitr ile containing some triethylamine. Dependent on the substitution patte rn of the starting material one obtains C,C- or C,O- coupling products . These represent the new ring system of trioxabicyclo[3.2.1]octenes 3 , which react with electrophiles and nucleophiles yielding tricyclic s ystems, whereas under hydrolytic conditions furans 14 may result.