The authors review the results of a wide variety of experiments on mat
erials such as La2CuO4 and Nd2CuO4 that contain weakly coupled CuO2 la
yers. These materials are antiferromagnetic insulators with very large
Heisenberg exchange energies, which become high-temperature supercond
uctors when charge carriers are added to the CuO2 layers. The growth o
f large single crystals has made it possible to carry out neutron scat
tering, as well as anisotropic optical, transport, and magnetization m
easurements. The properties of the undoped CuO2 layer are reviewed, an
d the evolution of magnetic, optical, and transport properties with th
e addition of charge carriers is discussed. The emphasis is on the pur
e and lightly doped materials, although the magnetism in the supercond
uctors is discussed. [S0034-6861(98)00403-6].