FURTHER STUDY OF THE AGOSTIC MOLECULE, TICL3 (DMPE) C2H5

Authors
COTTON FA PETRUKHINA MA
Citation
Fa. Cotton et Ma. Petrukhina, FURTHER STUDY OF THE AGOSTIC MOLECULE, TICL3 (DMPE) C2H5, INORGANIC CHEMISTRY COMMUNICATIONS, 1(6), 1998, pp. 195-196
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS → ACNP
ISSN journal
13877003
Volume
1
Issue
6
Year of publication
1998
Pages
195 - 196
Database
ISI
SICI code
1387-7003(1998)1:6<195:FSOTAM>2.0.ZU;2-B
Abstract
The molecular structure of the title compound has been redetermined by X-ray crystallography at 213(2) K with results generally in agreement with those previously reported. Its tendency to cocrystallize with Ti Cl4(dmpe) is noted. Preliminary results on its decomposition suggest a radical process, rather than beta-H transfer followed by C2H4 elimina tion. (C) 1998 Elsevier Science S.A. All rights reserved.