TUNING THE FLUOROUS PARTITION-COEFFICIENTS OF ORGANOMETALLIC COMPLEXES, THE SYNTHESIS AND CHARACTERIZATION OF [ETA(5)-C5H4CH2CH2(CF2)(9)CF3]RH(CO)L (L = CO OR P[CH2CH2(CF2)(5)CF3](3)) AND CL2NI(P[CH2CH2(CF2)(5)CF3](3))(2)

Authors
HERRERA V DEREGE PJF HORVATH IT LEHUSEBO T HUGHES RP
Citation
V. Herrera et al., TUNING THE FLUOROUS PARTITION-COEFFICIENTS OF ORGANOMETALLIC COMPLEXES, THE SYNTHESIS AND CHARACTERIZATION OF [ETA(5)-C5H4CH2CH2(CF2)(9)CF3]RH(CO)L (L = CO OR P[CH2CH2(CF2)(5)CF3](3)) AND CL2NI(P[CH2CH2(CF2)(5)CF3](3))(2), INORGANIC CHEMISTRY COMMUNICATIONS, 1(6), 1998, pp. 197-199
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS → ACNP
ISSN journal
13877003
Volume
1
Issue
6
Year of publication
1998
Pages
197 - 199
Database
ISI
SICI code
1387-7003(1998)1:6<197:TTFPOO>2.0.ZU;2-U
Abstract
[eta(5)-C5H4(CH2CH2(CF2)(9)CF3]Rh(CO)L (L = CO (1) or P[CH2CH2(CF2)(5) CF3](3) (2)) and Cl2Ni{P[CH2CH2(CF2)(5)CF3](3)}(2) (3) were prepared a nd characterized. The fluorous partition coefficients (P-FBS=c(Fluorou s) (phase)/c(Other phase)) of 1 (P-FBS=0.8), 2 (P-FBS=29), and 3 (P-FB S = 83) for the c-C6F11CF3/toluene fluorous biphase system (FBS) show that P-FBS can be increased significantly by increasing the number of perfluoroalkyl groups attached to the ligands. (C) 1998 Elsevier Scien ce S.A. All rights reserved.