EPR EVIDENCE OF TETRAHALOGENO(TRIPHENYLMETHYLIMIDO)RHENIUM(VI) COMPLEXES [RE(NC(C6H5)(3))X-4] (X = CL, BR)

Authors
VOIGT A ABRAM U KIRMSE R
Citation
A. Voigt et al., EPR EVIDENCE OF TETRAHALOGENO(TRIPHENYLMETHYLIMIDO)RHENIUM(VI) COMPLEXES [RE(NC(C6H5)(3))X-4] (X = CL, BR), INORGANIC CHEMISTRY COMMUNICATIONS, 1(6), 1998, pp. 203-205
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS → ACNP
ISSN journal
13877003
Volume
1
Issue
6
Year of publication
1998
Pages
203 - 205
Database
ISI
SICI code
1387-7003(1998)1:6<203:EEOTC>2.0.ZU;2-2
Abstract
The EPR detection of the formation of two tetrahologeno Re-VI (5d(1)) complexes containing a nitrogen bridge 'Re-N-E' (E=C+(C6H5)(3)) is des cribed. Their EPR parameters are compared to those of the [ReNX4](-) ( X = Cl, Br) parent complexes; spin-density changes are discussed. (C) 1998 Elsevier Science S.A. All rights reserved.