METAL-MEDIATED BARBIER-TYPE CARBONYL ALLYLATION UNDER SOLVENT-FREE CONDITIONS

Authors
YI XH HABERMAN JX LI CJ
Citation
Xh. Yi et al., METAL-MEDIATED BARBIER-TYPE CARBONYL ALLYLATION UNDER SOLVENT-FREE CONDITIONS, Synthetic communications, 28(16), 1998, pp. 2999-3009
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
16
Year of publication
1998
Pages
2999 - 3009
Database
ISI
SICI code
0039-7911(1998)28:16<2999:MBCAUS>2.0.ZU;2-D
Abstract
Zinc, tin, and indium mediated Barbier-type cross coupling between car bonyl compounds and allyl halides have been investigated without addit ional solvent. The indium mediated reactions proceed effectively under solvent free conditions. To a more limited extent, the reactions were found to be mediated by zinc and tin. Various carbonyl compounds are transformed into the corresponding allylation product in this way. No apparent competing pinacol-coupling or home-coupling of the allyl hali de was observed.