NEW ACYLNITROSO COMPOUNDS FOR THE ASYMMETRIC OXYAMINATION OF DIENES

Authors
GOUVERNEUR V MCCARTHY SJ MINEUR C BELOTTI D DIVE G GHOSEZ L
Citation
V. Gouverneur et al., NEW ACYLNITROSO COMPOUNDS FOR THE ASYMMETRIC OXYAMINATION OF DIENES, Tetrahedron, 54(35), 1998, pp. 10537-10554
Citations number
34
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
35
Year of publication
1998
Pages
10537 - 10554
Database
ISI
SICI code
0040-4020(1998)54:35<10537:NACFTA>2.0.ZU;2-0
Abstract
A series oi new enantiomerically pure acylnitroso compounds have been prepared and tested as dienophiles for the asymmetric oxyamination of dienes. Very high selectivities were obtained with acylnitroso compoun ds derived from diphenylmethoxymethyl pyrrolidine 2c, the C-2-symmetri c pyrrolidines 2d-e and camphorsultam 2f. (C) 1998 Elsevier Science Lt d. All rights reserved.