THE EXCHANGE-REACTION OF HYDROGEN-ATOMS IN THE SYSTEM STERICALLY HINDERED HYDROXYLAMINE-NITROXYL RADICAL

Authors
MALIEVSKII AD KOROTEEV SV
Citation
Ad. Malievskii et Sv. Koroteev, THE EXCHANGE-REACTION OF HYDROGEN-ATOMS IN THE SYSTEM STERICALLY HINDERED HYDROXYLAMINE-NITROXYL RADICAL, Russian chemical bulletin, 47(7), 1998, pp. 1287-1291
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
47
Issue
7
Year of publication
1998
Pages
1287 - 1291
Database
ISI
SICI code
1066-5285(1998)47:7<1287:TEOHIT>2.0.ZU;2-T
Abstract
The rate constants of the direct and reverse exchange reactions of the hydrogen atom in the system sterically-hindered nitroxyl radical-hydr oxylamine of the quinoline, imidazoline, pyrrolidine, and piperidine s eries as well as diarylhydroxylamine were determined. A scale of the r eductive abilities of the hydroxylamines was established. A low value of the isotope effect is typical of the reactions of hydrogen exchange in the systems hydroxylamine-nitroxyl radical.