THE INFLUENCE OF DETERGENTLESS MICROEMULSION ON THE KINETICS OF HYDROLYSIS OF DI(P-NITROPHENYL) METHYLPHOSPHONATE CATALYZED BY AMINES

Authors
BELSKII VE VALEEVA FG KUDRYAVTSEVA LA
Citation
Ve. Belskii et al., THE INFLUENCE OF DETERGENTLESS MICROEMULSION ON THE KINETICS OF HYDROLYSIS OF DI(P-NITROPHENYL) METHYLPHOSPHONATE CATALYZED BY AMINES, Russian chemical bulletin, 47(7), 1998, pp. 1302-1305
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
47
Issue
7
Year of publication
1998
Pages
1302 - 1305
Database
ISI
SICI code
1066-5285(1998)47:7<1302:TIODMO>2.0.ZU;2-V
Abstract
The influence of the detergentless water/oil microemulsion formed in t he n-hexane-water-2-propanol system on the kinetics of the hydrolysis of di(p-nitrophenyl) methyrphosphonate under the conditions of general base catalysis by primary, secondary, and tertiary aliphatic amines w as investigated. The leveling of the catalytic rate constants and basi cities of the amines was found for this reaction in a microemulsion. T he catalytic rate constants for the amines containing hydrophilic grou ps increase in microemulsions as compared to those in an aqueous mediu m, while the catalytic constants for the amines containing hydrophobic groups decrease.