SOLID-STATE REACTION OF A LEAD-TETRAACETATE METAL HALIDE SYSTEM WITH NAPHTHALENE UNDER MECHANICAL ACTIVATION

Authors
NIKISHIN GI SOKOVA LL MAKHAEV VD PETROVA LA IGNATENKO AV KAPUSTINA NI
Citation
Gi. Nikishin et al., SOLID-STATE REACTION OF A LEAD-TETRAACETATE METAL HALIDE SYSTEM WITH NAPHTHALENE UNDER MECHANICAL ACTIVATION, Russian chemical bulletin, 47(7), 1998, pp. 1353-1355
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
47
Issue
7
Year of publication
1998
Pages
1353 - 1355
Database
ISI
SICI code
1066-5285(1998)47:7<1353:SROALM>2.0.ZU;2-5
Abstract
A mechanically activated solid-state reaction of halogenation of napht hatene with a Pb(OAc)(4)-alkaline or alkaline-earth metal halide syste m was carried out to yield 1-halonaphthalene as the main reaction prod uct and 1,4-dihalonaphthalene. The solid-state halogenation of naphtha lene is more selective than a liquid-phase reaction.