In this paper we report a study of the electronic state in Fe0.64Ni0.3
6 (Invar) and Fe0.5Ni0.5 alloys using the Compton scattering technique
. Measurements were made on the polycrystalline alloys and also the pa
rent metals using 59.54keV radiation from a 5 Ci Am-241 source. In the
case of Invar, our data shows reasonable agreement with the rigid-ban
d APW calculation of Wakoh. The data on both the alloys are in good ag
reement with the superposition of Compton profiles of the pure constit
uent metals, weighted by their compositions, suggesting that there is
no charge transfer. A comparison with an earlier work on Fe0.51Ni0.49
has also been made.