INTRAZEOLITE PHOTOCHEMISTRY - 22 - ACID-BASE PROPERTIES OF COUMARIN 6- CHARACTERIZATION IN SOLUTION, THE SOLID-STATE, AND INCORPORATED INTO SUPRAMOLECULAR SYSTEMS
S. Corrent et al., INTRAZEOLITE PHOTOCHEMISTRY - 22 - ACID-BASE PROPERTIES OF COUMARIN 6- CHARACTERIZATION IN SOLUTION, THE SOLID-STATE, AND INCORPORATED INTO SUPRAMOLECULAR SYSTEMS, JOURNAL OF PHYSICAL CHEMISTRY B, 102(30), 1998, pp. 5852-5858
The spectroscopic properties of the dye coumarin 6 in solution are rep
orted. Relatively large shifts are seen in both the absorption and flu
orescence spectra upon protonation. The very large Stokes shift that i
s seen for the dye in its solid state and as the hydrochloride salt re
veals that the dye molecules are forming aggregates, which is a phenom
enon that is also seen in very high concentrations of coumarin 6 in so
lution. The acid-base properties of coumarin 6 in heterogeneous system
s such as zeolites and clays are also presented. We have found that th
is dye molecule is extremely sensitive to the presence of Lewis and Br
onsted sites and were able to detect acidity in the faujasite zeolite
NaY which is usually considered to be nonacidic. Two series of faujasi
te zeolites, one in which the Bronsted acidity increases and the other
in which the Lewis acidity increases, were also studied. The dication
of the dye was detected in both HY100 and CBV 740, the zeolites with
the highest Bronsted and highest Lewis acidity, respectively, used in
the present study. Due to the large shifts seen for coumarin 6 in its
neutral, monocation, and dication forms, both the absorption and fluor
escence spectra resulted in detection of two species of the dye in tho
se zeolites with intermediate acidity. The ability of coumarin 6 to se
nse small amounts of Lewis and Bronsted sites makes it an attractive m
olecule to study other systems as well.