T. Nasu et al., STUDY OF PT BOTTOM ELECTRODES USING HIGH-TEMPERATURE SPUTTERING FOR FERROELECTRIC MEMORIES WITH SRBI2TA2O9 (SBTO) FILM, JPN J A P 1, 37(7), 1998, pp. 4144-4148
Pt bottom electrodes for SrBi2Ta2O9 (SBTO) capacitors have been invest
igated for use in nonvolatile memories. A Pt thin film which is sputte
red at a temperature of 300 degrees C consists of enlarged columnar gr
ains, while a film sputtered at room temperature consists of fibrous c
olumnar rains. The formation mechanism of enlarged grains of the Pt fi
lm sputtered at 300 degrees C is dire to the fact that the film struct
ure changes with substrate temperature based on the structure-zone mod
el. The Pt bottom electrode which consists of the enlarged grains resu
lts in a decrease in the Ti diffusion path, leading to effective adhes
ion of Pt to a SiO2 film.