TRANSITION-METAL COMPLEXES OF 1,10-PHENANTHROLINE-5,6-DIONE AS EFFICIENT MEDIATORS FOR THE REGENERATION OF NAD-SYNTHESIS( IN ENZYMATIC)

Authors
HILT G STECKHAN E
Citation
G. Hilt et E. Steckhan, TRANSITION-METAL COMPLEXES OF 1,10-PHENANTHROLINE-5,6-DIONE AS EFFICIENT MEDIATORS FOR THE REGENERATION OF NAD-SYNTHESIS( IN ENZYMATIC), Journal of the Chemical Society, Chemical Communications, (22), 1993, pp. 1706-1707
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
22
Year of publication
1993
Pages
1706 - 1707
Database
ISI
SICI code
0022-4936(1993):22<1706:TCO1AE>2.0.ZU;2-R
Abstract
The complexation of 1,10-phenanthroline-5,6-dione by transition metals increases the catalytic turnover frequency by a factor of up to 17 fo r the aerobic-chemical and a factor of 14 for the indirect electrochem ical NAD+-regeneration for HLADH catalysed alcohol oxidations in compa rison with the uncomplexed phenanthrolinediones.