The decays of the high angular momentum, high spin F-4(0) states of th
e electron configuration 3s3p3d in aluminium-like ions (with three ele
ctrons outside a closed shell) have been identified in delayed spectra
of foil excited Ti, Fe and Ni ion beams. The line identifications wer
e aided by HXR, MCHF, and MCDF calculations and are corroborated by li
fetime measurements which demonstrate the differential longevity of th
e fine structure levels. A search for the related case of 1s2p3dF-4(0)
level decays in Li-like ions of Si, P and S failed.