MOSSBAUER-EFFECT STUDY OF THE MAGNETIC-ORDERING IN GDMN2HX

Citation
J. Przewoznik et al., MOSSBAUER-EFFECT STUDY OF THE MAGNETIC-ORDERING IN GDMN2HX, Journal of magnetism and magnetic materials, 187(3), 1998, pp. 337-344
Citations number
19
Categorie Soggetti
Material Science","Physics, Condensed Matter
ISSN journal
03048853
Volume
187
Issue
3
Year of publication
1998
Pages
337 - 344
Database
ISI
SICI code
0304-8853(1998)187:3<337:MSOTMI>2.0.ZU;2-R
Abstract
By means of Fe-57 Mossbauer spectroscopy, values of the average isomer shifts at 4.2 and 300 K, the average hyperfine field at 4.2 K and the magnetic ordering temperatures were measured for Gd((Fe0.01Mn0.99)-Fe -57)(2)H-x (0 less than or equal to x less than or equal to 4.2). The relative importance of the volume expansion and band effects due to hy drogen absorption were deduced from isomer shift changes. The nonlinea r increase of the magnetic ordering temperature values versus x and ab rupt increase of the average hyperfine field for x greater than or equ al to 2.5 were revealed. Using YMn2Hx, results as reference, the magni tude of the 4f-3d interaction versus Mn-Mn distance for GdMn2Hx was in ferred. (C) 1998 Elsevier Science B.V. All rights reserved.