Dah. Teagle et al., STRONTIUM AND OXYGEN ISOTOPIC CONSTRAINTS ON FLUID MIXING, ALTERATIONAND MINERALIZATION IN THE TAG HYDROTHERMAL DEPOSIT, Chemical geology, 149(1-2), 1998, pp. 1-24
Strontium- and oxygen-isotopic measurements of samples recovered from
the Trans-Atlantic Geotraverse (TAG) hydrothermal mound during Leg 158
of the Ocean Drilling Program provide important constraints on the na
ture of fluid-rock interactions during basalt alteration and mineraliz
ation within an active hydrothermal deposit. Fresh Mid-Ocean Ridge Bas
alt (MORB), with a Sr-87/Sr-86 of 0.7026, from the basement beneath th
e TAG mound was altered at both low and high temperatures by seawater
and altered at high temperature by near end-member black smoker fluids
. Pillow breccias occurring beneath the margins of the mound are local
ly recrystallized to chlorite by interaction with large volumes of con
ductively heated seawater (> 200 degrees C). The development of a sili
cified, sulfide-mineralized stockwork within the basaltic basement fol
lows a simple paragenetic sequence of chloritization followed by miner
alization and the development of a quartz + pyrite + paragonite stockw
ork cut by quartz-pyrite veins. Initial alteration involved the develo
pment of chloritic alteration halos around basalt clasts by reaction w
ith a Mg-bearing mixture of upwelling, high-temperature (> 300 degrees
C), black smoker-type fluid with a minor (< 10%) proportion of seawat
er. Continued high-temperature (> 300 degrees C) interaction between t
he wallrock and these Mg-bearing fluids results in the complete recrys
tallization of the wallrock to chlorite + quartz + pyrite. The quartz
+ pyrite + paragonite assemblage replaces the chloritized basalts, and
developed by reaction at 250-360 degrees C with end-member hydrotherm
al fluids having Sr-87/Sr-86 approximate to 0.7038, similar to present
-day vent fluids. The uniformity of the Sr-87/Sr-86 ratios of hydrothe
rmal assemblages throughout the mound and stockwork requires that the
Sr-87/Sr-86 ratio of end-member hydrothermal fluids has remained relat
ively constant for a time period longer than that required to change t
he interior thermal structure and plumbing network of the mound and un
derlying stockwork. Precipitation of anhydrite in breccias and as late
-stage veins throughout most of the mound and stockwork, down to at le
ast 125 mbsf, records extensive entrainment of seawater into the hydro
thermal deposit. Sr-87/Sr-86 ratios indicate that most of the anhydrit
e formed from approximate to 2:1 mixture of seawater and black smoker
fluids (65% +/- 15% seawater). Oxygen-isotopic compositions imply that
anhydrite precipitated at temperatures between 147 degrees C and 270
degrees C and require that seawater was conductively heated to between
100 degrees C and 180 degrees C before mixing and precipitation occur
red. Anhydrite from the TAG mound has a Sr-Ca partition coefficient K-
d = 0.60 +/- 0.28 (2 sigma ). This value is in agreement with the rang
e of experimentally determined partition coefficients (K-d approximate
to 0.27-0.73) and is similar to those calculated for anhydrite from a
ctive black smoker chimneys from 21 degrees N on the East Pacific Rise
. The delta(18)O(SO4) of TAG anhydrite brackets the value of seawater
sulfate oxygen (approximate to 9.5 parts per thousand). Dissolution of
anhydrite back into the oceans during episodes of hydrothermal quiesc
ence provides a mechanism of buffering seawater sulfate oxygen to an i
sotopically light composition, in addition to the precipitation and di
ssolution of anhydrite within the oceanic basement during hydrothermal
recharge at the mid-ocean ridges. (C) 1998 Elsevier Science B.V. All
rights reserved.