SUBPICOSECOND IR STUDY OF THE REACTIVE INTERMEDIATE IN AN ALKANE C-H BOND ACTIVATION REACTION BY CPRH(CO)(2)

Authors
ASBURY JB GHOSH HN YESTON JS BERGMAN RG LIAN TQ
Citation
Jb. Asbury et al., SUBPICOSECOND IR STUDY OF THE REACTIVE INTERMEDIATE IN AN ALKANE C-H BOND ACTIVATION REACTION BY CPRH(CO)(2), Organometallics, 17(16), 1998, pp. 3417-3419
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
16
Year of publication
1998
Pages
3417 - 3419
Database
ISI
SICI code
0276-7333(1998)17:16<3417:SISOTR>2.0.ZU;2-Z
Abstract
The reactive intermediate in a cyclohexane C-H bond activation reactio n by CpRh(CO)(2) has been identified as the cyclohexane solvate eta(5) -CPRh(CO)(C6H12) by sub-picosecond infrared spectroscopy.