RUTHENIUM-CATALYZED ASYMMETRIC HYDROSILYLATION OF KETONES AND IMINE

Authors
NISHIBAYASHI Y TAKEI I UEMURA S HIDAI M
Citation
Y. Nishibayashi et al., RUTHENIUM-CATALYZED ASYMMETRIC HYDROSILYLATION OF KETONES AND IMINE, Organometallics, 17(16), 1998, pp. 3420-3422
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
16
Year of publication
1998
Pages
3420 - 3422
Database
ISI
SICI code
0276-7333(1998)17:16<3420:RAHOKA>2.0.ZU;2-O
Abstract
Ruthenium complexes with (oxazolinylferrocenyl)phosphines, RuCl2(PPh3) ((oxazolinylferrocenyl)-phosphine), have been prepared and characteriz ed by spectroscopy. these ruthenium complexes are very effective catal ysts for asymmetric hydrosilylation of not only ketones but also an im ine to give the corresponding sec-alcohols (up to 97% ee) and a sec-am ine (88% ee) after acid hydrolysis, respectively.