ACCESS TO PLANAR CHIRALITY THROUGH CYCLOPLATINATION OF ((DIMETHYLAMINO)METHYL)FERROCENE BY CIS-[PTCL2(SOMEAR)(2)] (AR = PHENYL, P-TOLYL)

Authors
RYABOV AD PANYASHKINA IM POLYAKOV VA HOWARD JAK KUZMINA LG DATT MS SACHT C
Citation
Ad. Ryabov et al., ACCESS TO PLANAR CHIRALITY THROUGH CYCLOPLATINATION OF ((DIMETHYLAMINO)METHYL)FERROCENE BY CIS-[PTCL2(SOMEAR)(2)] (AR = PHENYL, P-TOLYL), Organometallics, 17(16), 1998, pp. 3615-3618
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
16
Year of publication
1998
Pages
3615 - 3618
Database
ISI
SICI code
0276-7333(1998)17:16<3615:ATPCTC>2.0.ZU;2-U
Abstract
A reaction between ((dimethylamino)methyl)ferrocene and the enantiomer ically pure complex cis-[PtCl2(S-SOMeC6H4Me-p)(2)] affords the two eas ily separable cycloplatinated SsRp and SsSp diastereoisomers 4 and 5, respectively. The absolute configuration of 4 was established by an X- ray study. Diastereomers 4 and 5 react with PPh3 to give enantiomers w ith the planar chirality only.