Pm. Johnson et al., HIGH-RESOLUTION HEAT-CAPACITY STUDIES OF THE HEXATIC-B-SMECTIC-F PHASE-TRANSITION IN LIQUID-CRYSTAL COMPOUNDS, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 58(2), 1998, pp. 1207-1210
High-resolution calorimetric data for several compounds exhibiting the
hexatic-B-smectic-F transition have been obtained. This transition in
volves the formation of tilt in the presence of bond orientational ord
er. Like most of the smectic-A-smectic-C transitions, which show no bo
nd orientational order, the heat-capacity anomaly of the hexatic-B-sme
ctic-F transition exhibits mean-field-like behavior and can be well de
scribed by an extended mean-field model.