R. Nesi et al., PHTHALONITRILES BY HETERO-DIELS-ALDER REACTIONS OF 4,5-DICYANOPYRIDAZINE WITH ENAMINES - ISOLATION AND CHARACTERIZATION OF UNPRECEDENTED INTERMEDIATES, Tetrahedron, 54(36), 1998, pp. 10851-10856
The title conversions were shown to involve as key intermediates new d
icyanodiene systems, that can be isolated in high yields under mild co
nditions; their structures, inferred from analytical and spectral data
, were confirmed by an X-ray study. Some improvements for the syntheti
c methodology connected with this finding are discussed. (C) 1998 Else
vier Science Ltd. All rights reserved.