UNUSUAL CHLORINATION OF SOME OLEFINS WITH META-CHLOROPERBENZOIC ACID IN DICHLOROMETHANE

Authors
LAKHRISSI M CARCHON G SCHLAMA T MIOSKOWSKI C CHAPLEUR Y
Citation
M. Lakhrissi et al., UNUSUAL CHLORINATION OF SOME OLEFINS WITH META-CHLOROPERBENZOIC ACID IN DICHLOROMETHANE, Tetrahedron letters, 39(36), 1998, pp. 6453-6456
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
36
Year of publication
1998
Pages
6453 - 6456
Database
ISI
SICI code
0040-4039(1998)39:36<6453:UCOSOW>2.0.ZU;2-2
Abstract
In the presence of poorly reactive olefins such as dichloroolefins, me ta-chloroperbenzoic acid reacts with dichloromethane, probably via a r adical mechanism, to produce a powerful chlorinating species which beh aves like other chlorinating agents. (C) 1998 Elsevier Science Ltd. Al l rights reserved.