TOTAL SYNTHESIS OF NPTX-5 AND NPTX-6, JORO SPIDER (NEPHILA-CLAVATA) TOXINS HAVING A UNIQUE PUTREANINE TRIMER AND PUTREANINE TETRAMER ACYLPOLYAMINE CHAIN
H. Saito et al., TOTAL SYNTHESIS OF NPTX-5 AND NPTX-6, JORO SPIDER (NEPHILA-CLAVATA) TOXINS HAVING A UNIQUE PUTREANINE TRIMER AND PUTREANINE TETRAMER ACYLPOLYAMINE CHAIN, Tetrahedron letters, 39(36), 1998, pp. 6479-6482
The first total synthesis of NPTX-5 and NPTX-6, Joro spider (Nephila c
lavata) toxins having a 4-hydroxyindole nucleus and a unique putreanin
e trimer and tetramer acylpolyamine chain, respectively, has been achi
eved by the iterative use of a key azide compound. (C) 1998 Elsevier S
cience Ltd. All rights reserved.