A. Dondoni et al., SYNTHESIS OF ETHYLENE ISOSTERES OF BETA-D-GALACTOSYL-ASPARAGINE AND BETA-D-GLUCOSYL-L-ASPARAGINE, Tetrahedron letters, 39(36), 1998, pp. 6601-6604
The Mukaiyama-type coupling of galactosyl and glucosyl aldehydes with
a four-carbon atom silyl enol ether carrying the oxazolidine ring affo
rds the corresponding sugar containing aldols (65-74%) that upon deoxy
genation and oxidative cleavage of the heterocyclic ring lead to the t
itle carbon-linked beta-glycosyl amino acids. (C) 1998 Elsevier Scienc
e Ltd. All rights reserved.