N. Ogawa et al., EVALUATION OF SEA-SALT ORIGIN POLLUTANTS IN PRECIPITATION AT AKITA USING CONSTRAINED OBLIQUE ROTATIONAL FACTOR-ANALYSIS, Bunseki Kagaku, 47(8), 1998, pp. 503-511
The validity of the classification of sea-salt and non-sea-salt origin
s of pollutants in precipitation was evaluated using a constrained obl
ique rotational factor analysis. The precipitations used for this anal
ysis were collected from April, 1993 to March, 1995 in Akita and from
January to March of 1994 and 1995 in Yuzawa on a day-after-day basis.
The chemical compositions in these precipitations were analyzed and th
eir four sub-data-sets (a two-year data-set of Akita, a data-set of wi
nter season in Akita, a data-set of seasons except for winter in Akita
and a data-set of winter season in Yuzawa) were analyzed using the fa
ctor analysis. Three or four pollutant sources were quantitatively ext
racted for each data-set. The factor analysis has extracted a factor a
scribed to the sea-salt (ss) component without using any information c
oncerning its composition. However, a part of the sodium and chloride
ion is also involved in another acidic factor, which contains sulfuric
acid. This means that part of sea-salt particles suffered a chemical
reaction while coming to the precipitation place from the Sea of Japan
.