THE FIRST EXAMPLE OF A DOUBLE BRIDGED DIRUTHENIUM(II) COMPLEX CONTAINING THE RARE BRIDGING S,O BIDENTATE DIMETHYL-SULFOXIDE LIGAND WHICH DEFINES A STABLE RU-CL-RU-S-O 5-MEMBERED RING

Authors
GEREMIA S MESTRONI S CALLIGARIS M ALESSIO E
Citation
S. Geremia et al., THE FIRST EXAMPLE OF A DOUBLE BRIDGED DIRUTHENIUM(II) COMPLEX CONTAINING THE RARE BRIDGING S,O BIDENTATE DIMETHYL-SULFOXIDE LIGAND WHICH DEFINES A STABLE RU-CL-RU-S-O 5-MEMBERED RING, Journal of the Chemical Society. Dalton transactions, (15), 1998, pp. 2447-2448
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
15
Year of publication
1998
Pages
2447 - 2448
Database
ISI
SICI code
0300-9246(1998):15<2447:TFEOAD>2.0.ZU;2-P
Abstract
The diruthenium(II) complex [Ru-2(mu-Cl)(mu-Me2SO-S, O)Cl-3(Me2SO-S)(3 )(CO)(2)] has been synthesized from cis,fac-[RuCl2(Me2SO)(3)(CO)] in r efluxing acetone and characterized by X-ray crystallography; unusual s olution (H-1 and C-13 NMR) and solid-state (IR) spectral features were found for the bridging sulfoxide, besides a remarkable inertness towa rds substitution reactions.