R. Holz et Fw. Schneider, CONTROL OF DYNAMIC STATES WITH TIME-DELAY BETWEEN 2 MUTUALLY FLOW-RATE COUPLED REACTORS, Journal of physical chemistry, 97(47), 1993, pp. 12239-12243
We present experiments and simulations of two mutually flow rate coupl
ed chemical oscillators (minimal bromate (MB) oscillators), where the
flow rate into one reactor is controlled by a species concentration (C
e4+) of the other reactor. A delay time T is introduced between the ou
tput (Ce4+ Concentration) of one reactor and the input (flow rate) int
o the other so that the state of one reactor at a certain time t is de
termined by the state of the other reactor at a previous time t - tau.
Chaos does not occur in this MB system. Here we report how to control
certain periodic and steady states. We observe two special phenomena,
namely, oscillator death and rhythmogenesis. Oscillator death is indu
ced by coupling two MB oscillatory states; as a result, two different
steady states are produced. The reverse phenomenon, rhythmogenesis, is
observed as the appearance of a common oscillatory state when two ide
ntical MB stationary states are coupled. Numerical calculations using
two coupled NFT models show good agreement with the experimental resul
ts.