Zm. Wang et Gj. Shiflet, GROWTH OF DELTA ON DISLOCATIONS IN A DILUTE AL-LI ALLOY, Metallurgical and materials transactions. A, Physical metallurgy andmaterials science, 29(8), 1998, pp. 2073-2085
The quantitative results of delta' growth kinetics on dislocations in
an Al-2.27 wt pet Li alloy demonstrate that at temperatures greater th
an 0.5 of the homologous melting temperature, T-m, volume diffusion is
the dominant mechanism. However, a small contribution, approximately
one atom in 300, is made by pipe diffusion through the dislocation. Th
is can be established by careful examination of dislocation climb asso
ciated with precipitate growth. An analysis based on the S' growth kin
etics and diffusion equation gives an activation energy of 0.56 eV for
Li pipe diffusion. At temperatures <0.5 T-m, delta' precipitate growt
h is faster when associated with dislocations, and here, pipe diffusio
n is necessary to account for the kinetics observed.