Rw. Fonda et al., THE EFFECT OF UNDERCOOLING ON THE CELLULAR PRECIPITATION REACTION IN CU-3 PCT TI, Metallurgical and materials transactions. A, Physical metallurgy andmaterials science, 29(8), 1998, pp. 2101-2110
The effect of undercooling on the morphology of the cellular precipita
tion reaction in Cu-3 Pet Ti is examined by scanning electron microsco
py (SEM, transmission electron microscopy (TEM), and serial sectioning
experiments. The reaction front formed at small undercooling, which e
xhibits strong faceting of the precipitate growth interfaces, graduall
y changes with increasing undercooling to a smoothly curved reaction f
ront with concave precipitate growth interfaces and convex grain bound
ary segments. This concealment of the faceted reaction front appears t
o be due to the rapid accumulation of growth ledges with increasing un
dercooling. This study also indicates that the cellular precipitation
reaction, at small undercooling, is initiated by Widmanstatten precipi
tation. At larger undercoolings, a second mechanism is responsible for
cellular genesis. Finally, contrary to accepted models of colony deve
lopment, serial sectioning experiments show that nucleation of additio
nal lamellae may occur at the faces of existing lamellae, from where t
hey extend laterally to achieve the characteristic interlamellar spaci
ng for that temperature.