L. Clarke et al., ROOM-TEMPERATURE COULOMB-BLOCKADE-DOMINATED TRANSPORT IN GOLD NANOCLUSTER STRUCTURES, Semiconductor science and technology, 13(8A), 1998, pp. 111-114
In this paper we discuss the near-room-temperature electrical transpor
t characteristics of structures made from ligand-stabilized metal clus
ters. The structures show threshold behaviour, nonlinear current-volta
ge characteristics and radio-frequency-induced plateaux consistent wit
h Coulomb-blockade-dominated transport in disordered arrays of metal d
ots. Samples having triphenylphosphine and octadecanethiol ligand shel
ls are found to have a 3 orders of magnitude difference in current abo
ve threshold. We discuss a possible explanation for this observation.