P. Pechukas et J. Ankerhold, MATHEMATICAL ASPECTS OF THE FLUCTUATING BARRIER PROBLEM - EXISTENCE OF EQUILIBRIUM AND RELAXATION SOLUTIONS, Chemical physics, 235(1-3), 1998, pp. 5-10
For the simplest fluctuating barrier rate problem - diffusion in a sym
metric double well over a barrier fluctuating randomly between 'high'
and 'low' - we prove the existence of equilibrium and relaxation eigen
vectors of the corresponding matrix of Smoluchowski diffusion operator
s, thereby establishing the validity of rate calculations for this pro
blem by the eigenvector-eigenvalue method. (C) 1998 Elsevier Science B
.V. All rights reserved.