The crystal structure of hydrated strontium decavanadate, Sr3V10O28.22
H(2)O, has been determined. It contains two types of strontium ions: t
he first is coordinated to seven water molecules which define a pentag
onal bipyramid; the second bonds to five molecules of water and three
O atoms of different decavanadate ions, thereby bridging between decav
anadate ions to produce layers of formula [Sr2V10O38H20](n) on the cry
stallographic plane (100). The heptacoordinated Sr and the five molecu
les of water associated with it are located between the different laye
rs.